Light-driven chemistry for a sustainable future
Discussion meeting organised by Professor Anatoly Zayats, Professor Stefan Maier, Sir Richard Catlow FRS, Professor Graham Hutchings CBE FRS.
Increasing demands on clean energy and a sustainable environment require a paradigm shift in catalysis and chemical industries to reduce energy consumption and the use of rare materials. Photonics offers new emerging solutions to control chemical processes with light. This meeting will bring together researchers across the disciplines of chemistry and optical physics to chart emerging routes for light-driven catalysis.
Poster session
There will be a poster session on Monday 1 June. Registered attendees will be invited to submit a proposed poster title and abstract (up to 200 words). Acceptances may be made on a rolling basis so we recommend submitting as soon as possible in case the session becomes full. Submissions made within one month of the meeting may not be included in the programme booklet.
Attending the event
This event is intended for researchers in relevant fields.
- Free to attend
- Both virtual and in-person attendance is available. Advance registration is essential
- Lunch is available on both days of the meeting for an optional £25 per day. There are plenty of places to eat nearby if you would prefer to purchase food offsite. Participants are welcome to bring their own lunch to the meeting
Enquiries: Scientific Programmes team.
Organisers
Schedule
Chair
Dr Aliaksandra Rakovich
King’s College London, UK
Dr Aliaksandra Rakovich
King’s College London, UK
| 09:00-09:05 |
Welcome by the Royal Society and lead organiser
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| 09:05-09:30 |
Chemistry in optical cavities
Professor Felipe Herrera
Professor Felipe Herrera |
| 09:30-09:45 |
Discussion
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| 09:45-10:15 |
Cavity-modulated chemical reactions
Professor Angel RubioMax Plank Institute for Structure and Dynamics of Matter at Hamburg, Germany
Professor Angel RubioMax Plank Institute for Structure and Dynamics of Matter at Hamburg, Germany Angel Rubio, born on 27 September 1965 in Oviedo, Spain, is the Director of the Theory Department of the Max Planck Institute for the Structure and Dynamics of Matter. He is also Distinguished Research Scientist at the Simons Foundation Flatiron Institute (NY, USA) and Professor/Chair for condensed matter physics at the University of the Basque Country in Donostia-San Sebastián, Spain. He received his PhD in Physics in 1991 from the University of Valladolid. He worked as post-doctoral researcher at University of California at Berkeley (1992-94). He is External Scientific Member of the Fritz Haber Institute in Berlin and Full Professor at the University of Hamburg (2016). He is acknowledged as a pioneer and leader in the area of computational materials physics, one of the founders of modern 'theoretical spectroscopy', and the originator of the widely used ab initio open-source project Octopus. Recently his research has focussed on the prediction and characterization of new non-equilibrium states of matter. His work has been recognized by several awards, including the 2018 Max Born medal and prize, 2016 Medal of the Spanish Royal Physical Society, the 2014 Premio Rey Jaime I for basic research, the 2006 DuPont Prize in nanotechnology, the 2005 Friedrich Wilhelm Bessel Research Award of the Humboldt Foundation, and two European Research Council advanced grants (2011 and 2016). Rubio is Fellow of the American Physical Society and the American Association for the Advancement of Science, member of the Academia Europaea, and a foreign associate member of the National Academy of Sciences. |
| 10:15-10:30 |
Discussion
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| 10:30-11:00 |
Break
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| 11:00-11:30 |
Sustainable plasmonic photocatalysis
Professor Naomi HalasRice University, US Professor Naomi HalasRice University, US |
| 11:30-11:45 |
Discussion
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| 11:45-12:15 |
Alchemical glazing of single atomic metallic layers for enhanced plasmonic catalysis
Plasmonic nanocavities offer exceptional confinement of light, making them promising for photocatalytic applications. However, optimal plasmonic metals are often unsuitable catalysts. Here we integrate ultrathin Pd ant Pt metal films from sub- to few- atomic monolayers inside plasmonic nanocavities using underpotential deposition. Despite their bulk metals having poor plasmonic properties in the visible region, minimal loss in optical field enhancement is delivered along with chemical enhancement. Such synergistic effects significantly enhance photocatalytic activity of the plasmonic nanocavities as well as photostability by suppressing surface atom migration. We also show how this enables real-time observation of electrocatalytic reactions down to the single molecule scale, improving understanding of real-world in-situ processes. This atomic alchemical-glazing approach is general for a range of catalytic metals that bridge plasmonic and chemical catalysis, yielding broad applications in photocatalysis for optimal chemical transformation.
Professor Jeremy J Baumberg FRSUniversity of Cambridge, UK
Professor Jeremy J Baumberg FRSUniversity of Cambridge, UK Professor Jeremy J Baumberg FRS, directs a UK Nano-Photonics Centre at the University of Cambridge and has extensive experience in developing optical materials structured on the nano-scale that can be assembled in large volume. He is also Director of the Cambridge Nano Doctoral Training Centre, a key UK site for training PhD students in interdisciplinary Nano research. Strong experience with Hitachi, IBM, his own spin-offs Mesophotonics and Base4, as well as strong industrial engagement give him a unique position to combine academic insight with industry application in a two-way flow. With over 20,000 citations, he is a leading innovator in Nano. This has led to awards of the Institute of Physics (IoP) Faraday Gold Medal (2017), Royal Society Rumford Medal (2014), IoP Young Medal (2013), Royal Society Mullard Prize (2005), the IoP Charles Vernon Boys Medal (2000) and the IoP Mott Lectureship (2005). He frequently talks on NanoScience to the media, and is a strategic advisor on NanoTechnology to the UK Research Councils. He is a Fellow of the Royal Society, the Optical Society of America, and the Institute of Physics. His recent popular science book The Secret Life of Science: How Science Really Works and Why it Matters is just published by PUP. |
| 12:15-12:30 |
Discussion
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| 13:30-14:00 |
Computer modelling of catalytic materials for light-driven CO2 conversion and hydrogen generation
Professor Nora de LeeuwUniversity of Leeds, UK
Professor Nora de LeeuwUniversity of Leeds, UK Nora de Leeuw is Professor of Computational Chemistry at the University of Leeds, where she also serves as Executive Dean of the Faculty of Engineering and Physical Sciences. With a PhD in Computational Chemistry from the University of Bath, she has held academic appointments at Cardiff University, where she was Pro-Vice Chancellor International; University College London, where she also led an EPSRC Centre for Doctoral Training; the University of Reading and Birkbeck College London, where she held an EPSRC Advanced Research Fellowship. Nora has been awarded a Royal Society Wolfson Merit Award, an AWE William Penney Fellowship, and a Royal Society Industry Fellowship. She is a Fellow of the Royal Society of Chemistry, elected Fellow of the Learned Society of Wales and elected Member of Academia Europaea. |
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| 14:00-14:15 |
Discussion
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| 14:15-14:45 |
Computational prediction of new transparent conducting oxides for band alignment matching in PEC and PV applications
Dr David ScanlonUniversity College London, UK Dr David ScanlonUniversity College London, UK David O Scanlon is a Reader in Computational, Inorganic and Materials Chemistry at University College London (UCL). He was awarded his PhD in Chemistry from Trinity College Dublin in 2011, and moved later that year to take up a Ramsay Fellowship in the Department of Chemistry at UCL. He leads a group focused on computationally driven materials design at UCL, especially within the remit of solid state materials for renewable energy applications. |
| 14:45-15:00 |
Discussion
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| 15:00-15:30 |
Break
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| 15:30-16:00 |
Theory of hot-electron chemistry
Professor Francesca BalettoUniversità degli Studi di Milano, Italy Professor Francesca BalettoUniversità degli Studi di Milano, Italy |
| 16:00-16:15 |
Discussion
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| 16:15-17:00 |
Poster flash talk session
Professor Stefan MaierImperial College London, UK
Professor Stefan MaierImperial College London, UK Stefan Maier is Head of School Physics and Astronomy at Monash University, and the Lee Lucas Chair in Experimental Physics at Imperial College London. His research covers nanophotonics, plasmonics, and metamaterials. He is the recipient of the Sackler Prize in the Physical Sciences, and a fellow of Optica, the Institute of Physics, and the Australian Institute of Physics. |
| 17:00-18:30 |
Poster session and drinks reception
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| 18:30-00:00 |
Close of meeting
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Chair
Professor Fang Xie
Imperial College London, UK
Professor Fang Xie
Imperial College London, UK
| 09:00-09:30 |
Nanophotonics for sustainable technologies and green energy
Professor Alexandra BoltassevaPurdue University, US
Professor Alexandra BoltassevaPurdue University, US Alexandra Boltasseva is a Ron and Dotty Garvin Tonjes Distinguished Professor of Electrical and Computer Engineering at Purdue University, USA. She received her PhD in electrical engineering at Technical University of Denmark, DTU in 2004. Boltasseva specializes in nanophotonics, quantum photonics, and optical materials. She is the 2023 recipient of the R.W. Wood Prize (Optica, formerly Optical Society of America), 2022 Guggenheim Fellow, 2018 Blavatnik National Award for Young Scientists Finalist and received the 2013 Institute for Electrical and Electronics Engineers (IEEE) Photonics Society Young Investigator Award, 2013 Materials Research Society (MRS) Outstanding Young Investigator Award, the 2011 MIT Technology Review Top Young Innovator (TR35), the 2009 Young Researcher Award in Advanced Optical Technologies from the University of Erlangen-Nuremberg, Germany, and the Young Elite-Researcher Award from the Danish Council for Independent Research (2008). She is a Fellow of the National Academy of Inventors (NAI), MRS, IEEE, Optica, and SPIE. |
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| 09:30-09:45 |
Discussion
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| 09:45-10:15 |
Sustainable future through photochemical reactions driven by quantum coherence
Professor Hiroaki MisawaHokkaido University, Japan Professor Hiroaki MisawaHokkaido University, Japan |
| 10:15-10:30 |
Discussion
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| 10:30-11:00 |
Break
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| 11:00-11:30 |
Converting methane to fuels with atomically-optimized plasmon catalysts
Professor Jennifer DionneStanford University, US
Professor Jennifer DionneStanford University, US Jennifer Dionne is an associate professor of Materials Science and Engineering at Stanford, and an affiliate faculty of the Stanford Neurosciences Institute, TomKat Center for Sustainable Energy, and Bio-X. Jen received her PhD in Applied Physics at the California Institute of Technology, advised by Harry Atwater, and BS degrees in Physics and Systems & Electrical Engineering from Washington University in St. Louis. Prior to joining Stanford, she served as a postdoctoral researcher in Chemistry at Berkeley, advised by Paul Alivisatos. Jen’s research develops new nanophotonic materials and microscopies to observe chemical and biological processes as they unfold with nanometer scale resolution. She then uses these observations to help improve energy-relevant processes (such as photocatalysis and energy storage) and medical diagnostics. Her work has been recognised with a Moore Inventor Fellowship (2017), the Materials Research Society Young Investigator Award (2017), Adolph Lomb Medal (2016), and Sloan Foundation Fellowship (2015), and was featured on Oprah’s list of '50 Things that will make you say ‘Wow’!'. She currently serves as director of the DOE-funded Photonics at Thermodynamic Limits Energy Frontier Research Center and faculty co-director of Stanford’s Photonics Research Center. |
| 11:30-11:45 |
Discussion
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| 11:45-12:15 |
Solar chemistry for low temperature NOx reduction
Professor Andy Beale, University College London, UK
Professor Andy Beale, University College London, UKAndrew M Beale is an EPSRC Early career Fellow and Professor of Inorganic Chemistry at UCL based at the Research Complex at Harwell, Rutherford Appleton Laboratories in Harwell, Didcot. He is also co-director of the spin-off company Finden Ltd. Current research interests fall mainly into the category of catalysis and solid-state chemistry particularly studied under dynamic or operando conditions. Specific areas of interest include the development of novel imaging techniques (‘multimodal’) for the study of single catalyst bodies/grains under real reaction conditions, determining the nature of the active site and reaction mechanism in catalysts for NOx abatement, methane activation/upgrading, unravelling the self-assembly mechanism of the microporous materials and the characterisation of catalytically active supported nanoparticles. |
| 12:15-12:30 |
Discussion
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Chair
Professor Christopher Hardacre
Queen's University Belfast, UK
Professor Christopher Hardacre
Queen's University Belfast, UK
Chris Hardacre is currently Head of the School of Chemistry and Chemical Engineering in Queen’s University, Belfast. He obtained a PhD from Cambridge University in 1994 and was an SERC research and a junior research fellow at Emmanuel College, Cambridge. He moved to Queen’s in 1995 as a lecturer in Physical Chemistry and in 2003, he was appointed as Professor of Physical Chemistry and became Director of Research of the Centre for the Theory and Application for Catalysis (CenTACat). In 2004 he was awarded a USAF, Window on Science visiting research fellowship. Through his work in ionic liquids research, he was awarded the Royal Society of Chemistry Encouraging Innovation Award with Merck Chemicals Ltd and was part of the team to win the Queen’s Anniversary Prize for Further and Higher Education. In 2008 he was awarded the US R and D 100 award for the development of spatially resolved measurements in catalytic monoliths with Alex Goguet (QUB) and colleagues from the Oak Ridge National Lab and in 2013 was the inaugural winner of the IChemE’s Andrew Medal for catalysis. He is a Co-PI for the UK Catalysis Hub and has research interests in the use of kinetic and spectroscopic techniques to determine gas phase and liquid phase heterogeneously catalysed reaction mechanisms for emission control catalysis, liquid phase hydrogenations and the conversion of biomass to fine chemicals. He published over 330 papers and 8 patents and has an H-index of 52l.
| 13:30-14:00 |
CH4 upgrading by photon-phonon co-driven catalysis
Small and inert molecules (eg CO2 and CH4) upgrading by solar energy is regarded as a pivotal approach to achieve carbon neutrality in chemical synthesis. Typically, we found that surface junctions can substantially facilitate charge transfer and separation generated by solar energy, which has been demonstrated by carbon quantum dots/C3N4 for an unprecedented CO2 conversion, leading to CO2 to methanol with a 100% selectivity [1]. More importantly, we discovered that coupling photons with phonons to co-drive catalytic reactions is significantly more efficient and selective compared to solely relying on photocatalysis, which has been demonstrated in a few scenarios, including methane conversion to formaldehyde on Ru/ZnO [2], to C2H6 over Au loaded TiO2 [3] etc, and very recently to ethanol on an intramolecular junction [4], all with extremely high conversion and selectivity. References
Professor Junwang TangTsinghua University, China
Professor Junwang TangTsinghua University, China Professor Junwang (John) Tang is a member of the Academia of Europaea, Fellow of the European Academy of Sciences, Fellow of RSC, Fellow of IMMM and Honorary Fellow of CCS. He is currently the Director of Industrial Catalysis Center and Carbon Neutrality Chair Professor of Materials Chemistry and Catalysis at Tsinghua University, China and Visiting Professor at University College London, UK. Tang has pioneered in coupling photons with phonons for small molecule activation to produce zero-carbon fuels (eg H2O to H2, N2 to NH3) and green chemicals (CO2 to alcohols and CH4 to long chain hydrocarbons) as well as microwave catalysis (eg chemical plastic recycling), together with the investigation of the underlying charge dynamics and kinetics by state-of-the-art spectroscopies. He is also the Editor / Associate Editor of five journals, including Appl Catal B, EES Solar etc. |
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| 14:00-14:15 |
Discussion
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| 14:15-14:45 |
Barriers to change in chemical manufacturing
Dr Susannah Scott, University of California, Santa Barbara, USA
Dr Susannah Scott, University of California, Santa Barbara, USASusannah Scott is a Distinguished Professor in Chemical Engineering and in Chemistry & Biochemistry at the University of California, Santa Barbara. She earned her PhD in Inorganic Chemistry from Iowa State University and conducted postdoctoral research at the Institut de recherches sur la catalyse in Lyon, France. In 1994, she joined the faculty of the University of Ottawa, Canada, where she was named a Canada Research Chair. In 2003, she moved to Santa Barbara, where she currently holds the Mellichamp Chair in Sustainable Catalysis. Recently, she delivered the Ipatieff Lecture at Northwestern, the Grace Hopper Lecture at the University of Pennsylvania, the Kurt Wohl Memorial Lecture at the University of Delaware, the Boulder Scientific Lecture at the Colorado State University, the Eastman Foundation Lectures at the University of California, Berkeley, and the Irving Wender Lecture at the Pennsylvania State University. In 2022, she chaired the Gordon Research Conference on Catalysis. Her research interests focus on the design of catalysts for the conversion of conventional and unconventional carbon-based feedstocks. |
| 14:45-15:00 |
Discussion
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| 15:00-15:30 |
Break
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| 15:30-15:45 |
Visible light promotion of copper catalyst towards acceptorless dehydrogenation reactions
Harnessing light to modulate catalytic behaviour offers new opportunities to design sustainable oxidation processes at mild conditions. Copper based catalysts represent an attractive, earth abundant alternative to traditional noble metals for acceptorless dehydrogenation reactions, but their practical application is limited by surface oxidation and requirement for pre-reduction to access the active metallic phase. This work investigates how visible light illumination modulates catalytic performance and structure towards acceptorless dehydrogenation reactions to produce ketones and molecular H2 as a by-product. Visible light illumination of Cu/TiO₂ systems prepared by a colloidal deposition route induces marked enhancements in catalytic performance, with higher reaction rates and significantly shortened induction periods compared to purely thermally driven operation. These effects suggest that light accelerates the reduction of surface copper oxides and promotes the formation of active Cu⁰ sites which is supported by NAP-XPS measurements. Kinetic analysis demonstrates a substantial decrease in “apparent” activation energy under light assisted conditions allowing higher reaction rates to be achieved with lower thermal energy input while maintaining high selectivity. The results not only reveal how localised surface plasmon effects of Cu nanoparticles can be exploited to activate base metal catalysts at lower temperatures and show that tuning catalyst–light interactions can optimise selectivity and efficiency. By connecting photophysical processes with catalytic turnover, this work highlights the potential of light powered approaches to expand the chemical space accessible to earth abundant materials and reduce the carbon and energy intensity of oxidation chemistry. Dr Simon FreakleyUniversity of Bath, UK Dr Simon FreakleyUniversity of Bath, UK |
| 15:45-16:00 |
Thermal and electronic effects in plasmonic nanostructures for chiral catalysis
Dr Ouardia AkdimCardiff University, UK Dr Ouardia AkdimCardiff University, UK |
| 16:00-16:15 |
Discussion
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| 16:15-17:00 |
Panel discussion: Overview and future directions
Professor Anatoly ZayatsKing's College London, UK
Professor Anatoly ZayatsKing's College London, UK Professor Anatoly V Zayats is the head of the Photonics & Nanotechnology at the Department of Physics, King’s College London, where he also leads Nano-optics and Near-field Spectroscopy Laboratory. He is a Co-Director of the London Centre for Nanotechnology and the London Institute of Advanced Light Technologies. His current research interests are in the areas of nanophotonics, plasmonics, metamaterials, plasmocatalysis, nonlinear and ultrafast optics and spectroscopy, photonic spin-orbit interactions, and optical properties of surfaces, thin films, semiconductors and low-dimensional structures. He is a founding Editor-in-Chief of Advanced Photonics journal. He is a Fellow of the Institute of Physics, the Optical Society of America, SPIE, the Royal Society of Chemistry and elected Member of Academia Europaea. |
| 17:00-00:00 |
Close
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